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Professor Brian E Mann
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Professor Brian E Mann
  • Home
  • Research
  • Publications
    • Papers
    • Reviews
    • Reports
  • More
    • Home
    • Research
    • Publications
      • Papers
      • Reviews
      • Reports

Research

Recent research highlights

The use of metal carbonyls as pharmaceuticals

Mechanisms of Fluxionality

  • Demonstration of the low energy fluxional mechanism in Fe₃(CO)₁₂

  • Demonstration of the merry-go-round mechanism in Cp₂Mo₂(CO)₆

  • Demonstration of the trigonal twist mechanism in RuH₂(CO)(PPh₃)₃

  • Demonstration of the coexistence of Ir₄(µ-CO)₃(CO)₈(PH₂Ph) and Ir₄(CO)₁₁(PH₂Ph) on the merry-go-round pathway

Catalysis

  • Proof of the existence of [RhCl(CH₃)(CO)I₃]- in the catalytic cycle of the Monsanto process

  • Determination of the mechanism of the reaction of RuCl(H)(PPh₃)₃ with dienes and trienes

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